| Journée | Time (UTC) | Home | Score | Away |
|---|
| 1 | Mon, 19 Aug 2024, 7:30 pm | Villarreal  | 2 – 2 |  Atlético Madrid |
| 2 | Fri, 23 Aug 2024, 7:30 pm | Sevilla  | 1 – 2 | Villarreal |
| 3 | Mon, 26 Aug 2024, 7:30 pm | Villarreal | 4 – 3 |  Celta Vigo |
| 4 | Sat, 31 Aug 2024, 7:30 pm | Valencia  | 1 – 1 | Villarreal |
| 5 | Sat, 14 Sep 2024, 12:00 am | Mallorca  | 1 – 2 | Villarreal |
| 6 | Sun, 22 Sep 2024, 4:30 pm | Villarreal | 1 – 5 |  Barcelona |
| 7 | Thu, 26 Sep 2024, 5:00 pm | Espanyol  | 1 – 2 | Villarreal |
| 8 | Mon, 30 Sep 2024, 7:00 pm | Villarreal | 3 – 1 |  Las Palmas |
| 9 | Sat, 05 Oct 2024, 7:00 pm | Real Madrid  | 2 – 0 | Villarreal |
| 10 | Sun, 20 Oct 2024, 4:30 pm | Villarreal | 1 – 1 |  Getafe |
| 11 | Sat, 26 Oct 2024, 12:00 am | Valladolid  | 1 – 2 | Villarreal |
| 12 | Wed, 18 Dec 2024, 8:30 pm | Villarreal | 1 – 1 |  Rayo Vallecano |
| 13 | Sat, 09 Nov 2024, 3:15 pm | Villarreal | 3 – 0 |  Alavés |
| 14 | Sun, 24 Nov 2024, 1:00 pm | Osasuna  | 2 – 2 | Villarreal |
| 15 | Sun, 01 Dec 2024, 1:00 pm | Villarreal | 2 – 2 |  Girona |
| 16 | Sun, 08 Dec 2024, 3:15 pm | Athletic Bilbao  | 2 – 0 | Villarreal |
| 17 | Sun, 15 Dec 2024, 5:30 pm | Villarreal | 1 – 2 |  Real Betis |
| 18 | Sun, 22 Dec 2024, 5:30 pm | Leganés  | 2 – 5 | Villarreal |
| 19 | Sun, 12 Jan 2025, 5:00 pm | Real Sociedad  | 1 – 0 | Villarreal |
| 20 | Mon, 20 Jan 2025, 8:00 pm | Villarreal | 4 – 0 | Mallorca |
| 21 | Mon, 27 Jan 2025, 3:15 pm | Atlético Madrid | 1 – 1 | Villarreal |
| 22 | Sat, 01 Feb 2025, 3:15 pm | Villarreal | 5 – 1 | Valladolid |
| 23 | Sat, 08 Feb 2025, 5:30 pm | Las Palmas | 1 – 2 | Villarreal |
| 24 | Sat, 15 Feb 2025, 8:00 pm | Villarreal | 1 – 1 | Valencia |
| 25 | Sat, 22 Feb 2025, 3:15 pm | Rayo Vallecano | 0 – 1 | Villarreal |
| 26 | Mon, 03 Mar 2025, 8:00 pm | Villarreal | – | Espanyol |
| 27 | Sat, 08 Mar 2025, 3:15 pm | Alavés | 1 – 0 | Villarreal |
| 28 | Sat, 15 Mar 2025, 5:30 pm | Villarreal | 1 – 2 | Real Madrid |
| 29 | Sun, 30 Mar 2025, 12:00 am | Getafe | 1 – 2 | Villarreal |
| 30 | Sun, 06 Apr 2025, 7:00 pm | Villarreal | – | Athletic Bilbao |
| 31 | Sun, 13 Apr 2025, 4:30 pm | Real Betis | – | Villarreal |
| 32 | Sun, 20 Apr 2025, 2:15 pm | Villarreal | – | Real Sociedad |
| 33 | Wed, 23 Apr 2025, 4:00 pm | Celta Vigo | – | Villarreal |
| 34 | Sun, 04 May 2025, 4:00 pm | Villarreal | – | Osasuna |
| 35 | Sun, 11 May 2025, 4:00 pm | Girona | – | Villarreal |
| 36 | Wed, 14 May 2025, 4:00 pm | Villarreal | – | Leganés |
| 37 | Sun, 18 May 2025, 4:00 pm | Barcelona | – | Villarreal |
| 38 | Sun, 25 May 2025, 4:00 pm | Villarreal | – | Sevilla |
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Marcelino